E-ISSN 2063-5346
 

Original Article 
ECB. 2014; 3(4): 367-371


SELF-ASSEMBLY OF SUPRAMOLECULAR COMPLEX OF Zn(II) AND 2,7-DITHIO-3,6-DIAZAOCTADIEN-3,5-DITHIOAMIDE-1,8 IN AN IMMOBILIZED Zn2[Fe(CN)6]-GELATIN MATRIX

Oleg V. Mikhailov, Denis V. Chachkov.

Abstract
A new complex formation process was occurred in the Zn(II)–ethanedithioamide–ethanedial three-components system when a nanoreactor consist of zinc(II) hexacyanoferrate(II)-gelatin immobilized matrix was contacted with an aq. alkaline (pH~12) solutions containing
ethanedithioamide and ethanedial. It has been shown that self-assembly (template synthesis) of supramolecular (555)macrotricyclic Zn(II)
coordination compound with chelating ligand 2,7-dithio-3,6-diazaoctadien-3,5-dithioamide-1,8 occurs under these conditions. Besides,
ethanedithioamide and ethanedial act as ligand synthons in this process.

Key words: template synthesis; gelatin-immobilized matrix; zinc(II) ethanedithioamide; DFT method; 2,7-dithio-3,6-diazaoctadien-3,5-dithioamide-1,8; self-assembly


 
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Pubmed Style

Oleg V. Mikhailov, Denis V. Chachkov. SELF-ASSEMBLY OF SUPRAMOLECULAR COMPLEX OF Zn(II) AND 2,7-DITHIO-3,6-DIAZAOCTADIEN-3,5-DITHIOAMIDE-1,8 IN AN IMMOBILIZED Zn2[Fe(CN)6]-GELATIN MATRIX. ECB. 2014; 3(4): 367-371.


Web Style

Oleg V. Mikhailov, Denis V. Chachkov. SELF-ASSEMBLY OF SUPRAMOLECULAR COMPLEX OF Zn(II) AND 2,7-DITHIO-3,6-DIAZAOCTADIEN-3,5-DITHIOAMIDE-1,8 IN AN IMMOBILIZED Zn2[Fe(CN)6]-GELATIN MATRIX. https://www.eurchembull.com/?mno=55770 [Access: August 09, 2022].


AMA (American Medical Association) Style

Oleg V. Mikhailov, Denis V. Chachkov. SELF-ASSEMBLY OF SUPRAMOLECULAR COMPLEX OF Zn(II) AND 2,7-DITHIO-3,6-DIAZAOCTADIEN-3,5-DITHIOAMIDE-1,8 IN AN IMMOBILIZED Zn2[Fe(CN)6]-GELATIN MATRIX. ECB. 2014; 3(4): 367-371.



Vancouver/ICMJE Style

Oleg V. Mikhailov, Denis V. Chachkov. SELF-ASSEMBLY OF SUPRAMOLECULAR COMPLEX OF Zn(II) AND 2,7-DITHIO-3,6-DIAZAOCTADIEN-3,5-DITHIOAMIDE-1,8 IN AN IMMOBILIZED Zn2[Fe(CN)6]-GELATIN MATRIX. ECB. (2014), [cited August 09, 2022]; 3(4): 367-371.



Harvard Style

Oleg V. Mikhailov, Denis V. Chachkov (2014) SELF-ASSEMBLY OF SUPRAMOLECULAR COMPLEX OF Zn(II) AND 2,7-DITHIO-3,6-DIAZAOCTADIEN-3,5-DITHIOAMIDE-1,8 IN AN IMMOBILIZED Zn2[Fe(CN)6]-GELATIN MATRIX. ECB, 3 (4), 367-371.



Turabian Style

Oleg V. Mikhailov, Denis V. Chachkov. 2014. SELF-ASSEMBLY OF SUPRAMOLECULAR COMPLEX OF Zn(II) AND 2,7-DITHIO-3,6-DIAZAOCTADIEN-3,5-DITHIOAMIDE-1,8 IN AN IMMOBILIZED Zn2[Fe(CN)6]-GELATIN MATRIX. European Chemical Bulletin, 3 (4), 367-371.



Chicago Style

Oleg V. Mikhailov, Denis V. Chachkov. "SELF-ASSEMBLY OF SUPRAMOLECULAR COMPLEX OF Zn(II) AND 2,7-DITHIO-3,6-DIAZAOCTADIEN-3,5-DITHIOAMIDE-1,8 IN AN IMMOBILIZED Zn2[Fe(CN)6]-GELATIN MATRIX." European Chemical Bulletin 3 (2014), 367-371.



MLA (The Modern Language Association) Style

Oleg V. Mikhailov, Denis V. Chachkov. "SELF-ASSEMBLY OF SUPRAMOLECULAR COMPLEX OF Zn(II) AND 2,7-DITHIO-3,6-DIAZAOCTADIEN-3,5-DITHIOAMIDE-1,8 IN AN IMMOBILIZED Zn2[Fe(CN)6]-GELATIN MATRIX." European Chemical Bulletin 3.4 (2014), 367-371. Print.



APA (American Psychological Association) Style

Oleg V. Mikhailov, Denis V. Chachkov (2014) SELF-ASSEMBLY OF SUPRAMOLECULAR COMPLEX OF Zn(II) AND 2,7-DITHIO-3,6-DIAZAOCTADIEN-3,5-DITHIOAMIDE-1,8 IN AN IMMOBILIZED Zn2[Fe(CN)6]-GELATIN MATRIX. European Chemical Bulletin, 3 (4), 367-371.