E-ISSN 2063-5346
 

Original Article 
ECB. 2016; 5(3): 108-112


COPOLYMERIZATION OF 2-(4-VINYLPHENYL)CYCLOPROPYLMETHYL CINNAMATE WITH GLYCIDYL METHACRYLATE

K. G. Guliyev, A. M. Aliyeva, S. B. Mamedli, D. R. Nurullayeva, A. M. Guliyev.

Abstract
The radical copolymerization of 2-(4-vinylphenyl)cyclopropylmethyl cinnamate with glycidyl methacrylate has been studied and new
cyclopropane- and epoxy-group containing photosensitive copolymers have been prepared. The relative activity of monomers and the
parameters of Q and e by Alfrey and Price method have been determined. The copolymerization constants of 2-(4-
vinylphenyl)cyclopropylmethyl cinnamate (r1) and glycidyl methacrylate (r2) were determined by the Fineman-Ross method and proved to
be r1 = 1.05 and r2 = 0.4, respectively; the parameters Q1 and e1 were found to be 1.82, -0.79, respectively. The composition and structure
of this copolymer have been established. The photochemical investigations of the synthesized copolymer have been carried out. It has been
established that during the photochemical transformation a re-structuring takes place due to cyclopropane and epoxide ring opening and
reaction of double bond in cinnamate fragment as well

Key words: microstructure; monomers; copolymerisation; 2-(4-vinylphenyl)cyclopropylmethyl cinnamate; photosensitivity


 
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How to Cite this Article
Pubmed Style

K. G. Guliyev, A. M. Aliyeva, S. B. Mamedli, D. R. Nurullayeva, A. M. Guliyev. COPOLYMERIZATION OF 2-(4-VINYLPHENYL)CYCLOPROPYLMETHYL CINNAMATE WITH GLYCIDYL METHACRYLATE. ECB. 2016; 5(3): 108-112.


Web Style

K. G. Guliyev, A. M. Aliyeva, S. B. Mamedli, D. R. Nurullayeva, A. M. Guliyev. COPOLYMERIZATION OF 2-(4-VINYLPHENYL)CYCLOPROPYLMETHYL CINNAMATE WITH GLYCIDYL METHACRYLATE. https://www.eurchembull.com/?mno=69470 [Access: August 09, 2022].


AMA (American Medical Association) Style

K. G. Guliyev, A. M. Aliyeva, S. B. Mamedli, D. R. Nurullayeva, A. M. Guliyev. COPOLYMERIZATION OF 2-(4-VINYLPHENYL)CYCLOPROPYLMETHYL CINNAMATE WITH GLYCIDYL METHACRYLATE. ECB. 2016; 5(3): 108-112.



Vancouver/ICMJE Style

K. G. Guliyev, A. M. Aliyeva, S. B. Mamedli, D. R. Nurullayeva, A. M. Guliyev. COPOLYMERIZATION OF 2-(4-VINYLPHENYL)CYCLOPROPYLMETHYL CINNAMATE WITH GLYCIDYL METHACRYLATE. ECB. (2016), [cited August 09, 2022]; 5(3): 108-112.



Harvard Style

K. G. Guliyev, A. M. Aliyeva, S. B. Mamedli, D. R. Nurullayeva, A. M. Guliyev (2016) COPOLYMERIZATION OF 2-(4-VINYLPHENYL)CYCLOPROPYLMETHYL CINNAMATE WITH GLYCIDYL METHACRYLATE. ECB, 5 (3), 108-112.



Turabian Style

K. G. Guliyev, A. M. Aliyeva, S. B. Mamedli, D. R. Nurullayeva, A. M. Guliyev. 2016. COPOLYMERIZATION OF 2-(4-VINYLPHENYL)CYCLOPROPYLMETHYL CINNAMATE WITH GLYCIDYL METHACRYLATE. European Chemical Bulletin, 5 (3), 108-112.



Chicago Style

K. G. Guliyev, A. M. Aliyeva, S. B. Mamedli, D. R. Nurullayeva, A. M. Guliyev. "COPOLYMERIZATION OF 2-(4-VINYLPHENYL)CYCLOPROPYLMETHYL CINNAMATE WITH GLYCIDYL METHACRYLATE." European Chemical Bulletin 5 (2016), 108-112.



MLA (The Modern Language Association) Style

K. G. Guliyev, A. M. Aliyeva, S. B. Mamedli, D. R. Nurullayeva, A. M. Guliyev. "COPOLYMERIZATION OF 2-(4-VINYLPHENYL)CYCLOPROPYLMETHYL CINNAMATE WITH GLYCIDYL METHACRYLATE." European Chemical Bulletin 5.3 (2016), 108-112. Print.



APA (American Psychological Association) Style

K. G. Guliyev, A. M. Aliyeva, S. B. Mamedli, D. R. Nurullayeva, A. M. Guliyev (2016) COPOLYMERIZATION OF 2-(4-VINYLPHENYL)CYCLOPROPYLMETHYL CINNAMATE WITH GLYCIDYL METHACRYLATE. European Chemical Bulletin, 5 (3), 108-112.