E-ISSN 2063-5346
 

Original Article 
ECB. 2021; 10(2): 128-133


SYNTHESIS, SPECTROSCOPIC AND LUMENESCENT PROPERTIES OF ZINC COMPLEXES OF (4- OCTYLOXYPHENOXY)-SUBSTITUTED PHTHALOCYANINES

Dmitry Erzunov, Tatiana Tikhomirova, Anastasia Fedotova, Vladimir Maizlish, Arthur Vashurin.

Abstract
The work is devoted to the preparation of zinc complexes of tetra(4-octyloxyphenoxy)phthalocyanines, as well as its sulfonated derivatives
and the study of their properties, primarily spectroscopic and luminescent. The compounds were synthesized and characterized by IR and
electron spectroscopy, MALDI-TOF mass spectrometry and elemental analysis. Absorption spectra were obtained in the visible range in
chloroform, DMF, water (for the sulfonated analogue). It was shown that in the studied concentration range the complexes exist in
monomeric form. Sulfonated phthalocyaninates turned out to be aggregated only in an aqueous medium, which made it possible to study
the fluorescent properties in an organic medium (namely, in DMSO). The introduction of a sulfonate groups was found to lead to quenching
of fluorescence in comparison with an organo-soluble phthalocyaninate.

Key words: Phthalocyanine; synthesis; metal complexes; fluorescence; absorption spectroscopy


 
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Pubmed Style

Dmitry Erzunov, Tatiana Tikhomirova, Anastasia Fedotova, Vladimir Maizlish, Arthur Vashurin. SYNTHESIS, SPECTROSCOPIC AND LUMENESCENT PROPERTIES OF ZINC COMPLEXES OF (4- OCTYLOXYPHENOXY)-SUBSTITUTED PHTHALOCYANINES. ECB. 2021; 10(2): 128-133.


Web Style

Dmitry Erzunov, Tatiana Tikhomirova, Anastasia Fedotova, Vladimir Maizlish, Arthur Vashurin. SYNTHESIS, SPECTROSCOPIC AND LUMENESCENT PROPERTIES OF ZINC COMPLEXES OF (4- OCTYLOXYPHENOXY)-SUBSTITUTED PHTHALOCYANINES. https://www.eurchembull.com/?mno=83554 [Access: November 29, 2022].


AMA (American Medical Association) Style

Dmitry Erzunov, Tatiana Tikhomirova, Anastasia Fedotova, Vladimir Maizlish, Arthur Vashurin. SYNTHESIS, SPECTROSCOPIC AND LUMENESCENT PROPERTIES OF ZINC COMPLEXES OF (4- OCTYLOXYPHENOXY)-SUBSTITUTED PHTHALOCYANINES. ECB. 2021; 10(2): 128-133.



Vancouver/ICMJE Style

Dmitry Erzunov, Tatiana Tikhomirova, Anastasia Fedotova, Vladimir Maizlish, Arthur Vashurin. SYNTHESIS, SPECTROSCOPIC AND LUMENESCENT PROPERTIES OF ZINC COMPLEXES OF (4- OCTYLOXYPHENOXY)-SUBSTITUTED PHTHALOCYANINES. ECB. (2021), [cited November 29, 2022]; 10(2): 128-133.



Harvard Style

Dmitry Erzunov, Tatiana Tikhomirova, Anastasia Fedotova, Vladimir Maizlish, Arthur Vashurin (2021) SYNTHESIS, SPECTROSCOPIC AND LUMENESCENT PROPERTIES OF ZINC COMPLEXES OF (4- OCTYLOXYPHENOXY)-SUBSTITUTED PHTHALOCYANINES. ECB, 10 (2), 128-133.



Turabian Style

Dmitry Erzunov, Tatiana Tikhomirova, Anastasia Fedotova, Vladimir Maizlish, Arthur Vashurin. 2021. SYNTHESIS, SPECTROSCOPIC AND LUMENESCENT PROPERTIES OF ZINC COMPLEXES OF (4- OCTYLOXYPHENOXY)-SUBSTITUTED PHTHALOCYANINES. European Chemical Bulletin, 10 (2), 128-133.



Chicago Style

Dmitry Erzunov, Tatiana Tikhomirova, Anastasia Fedotova, Vladimir Maizlish, Arthur Vashurin. "SYNTHESIS, SPECTROSCOPIC AND LUMENESCENT PROPERTIES OF ZINC COMPLEXES OF (4- OCTYLOXYPHENOXY)-SUBSTITUTED PHTHALOCYANINES." European Chemical Bulletin 10 (2021), 128-133.



MLA (The Modern Language Association) Style

Dmitry Erzunov, Tatiana Tikhomirova, Anastasia Fedotova, Vladimir Maizlish, Arthur Vashurin. "SYNTHESIS, SPECTROSCOPIC AND LUMENESCENT PROPERTIES OF ZINC COMPLEXES OF (4- OCTYLOXYPHENOXY)-SUBSTITUTED PHTHALOCYANINES." European Chemical Bulletin 10.2 (2021), 128-133. Print.



APA (American Psychological Association) Style

Dmitry Erzunov, Tatiana Tikhomirova, Anastasia Fedotova, Vladimir Maizlish, Arthur Vashurin (2021) SYNTHESIS, SPECTROSCOPIC AND LUMENESCENT PROPERTIES OF ZINC COMPLEXES OF (4- OCTYLOXYPHENOXY)-SUBSTITUTED PHTHALOCYANINES. European Chemical Bulletin, 10 (2), 128-133.