E-ISSN 2063-5346
 

Original Article 
ECB. 2014; 3(6): 559-562


SYNTHESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH TRIDENTATE N3 DONOR SCHIFF BASE DERIVED FROM 2-AMINOTHIAZOLE

Mahmoud Najim Al-Jibouri, Fadhil R. Hafidh, Anaam Majeed Rasheed.

Abstract
A 2,6-diacetylpyridine based novel acyclic tridentate compartmental ligand (E)-N-(1-(6-((E)-1-(thiazol-5-ylimino)ethyl)pyridin-2-
yl)ethylidene)thiazol-2-amine was prepared by condensation of 2,6-diacetylpyridine and two equivalent of 2-thiazolamine in ethanol. The
reaction of metal chlorides (Mn(II), Co(II), Ni(II), Cu(II), Zn(II)) and VOSO4.5H2O with the new ligand in methanol results the formation
of deep colored metal complexes with the formula [MLCl]Cl (M=Mn, Ni, and Zn), [MLCl2(H2O)], M=Co, Cu(II), and [VOL(SO4)],
respectively. The free ligand and its metal complexes were characterized by elemental analyses, conductivity measurements, magnetic
susceptibility data, IR, UV-Vis and NMR spectral data. The physical measurements and FTIR spectral data showed that most of the
complexes contain tetrahedrally coordinated central ion(II) except the square-pyramidal vanadyl complex and octahedral geometry for
Co(II) and Cu(II) complexes.

Key words: Schiff base of 2,6-diacetylpyridine and 2-thiazolamine; metal complexes of acyclic ligands;


 
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Pubmed Style

Mahmoud Najim Al-Jibouri, Fadhil R. Hafidh, Anaam Majeed Rasheed. SYNTHESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH TRIDENTATE N3 DONOR SCHIFF BASE DERIVED FROM 2-AMINOTHIAZOLE. ECB. 2014; 3(6): 559-562.


Web Style

Mahmoud Najim Al-Jibouri, Fadhil R. Hafidh, Anaam Majeed Rasheed. SYNTHESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH TRIDENTATE N3 DONOR SCHIFF BASE DERIVED FROM 2-AMINOTHIAZOLE. https://www.eurchembull.com/?mno=57794 [Access: June 23, 2022].


AMA (American Medical Association) Style

Mahmoud Najim Al-Jibouri, Fadhil R. Hafidh, Anaam Majeed Rasheed. SYNTHESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH TRIDENTATE N3 DONOR SCHIFF BASE DERIVED FROM 2-AMINOTHIAZOLE. ECB. 2014; 3(6): 559-562.



Vancouver/ICMJE Style

Mahmoud Najim Al-Jibouri, Fadhil R. Hafidh, Anaam Majeed Rasheed. SYNTHESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH TRIDENTATE N3 DONOR SCHIFF BASE DERIVED FROM 2-AMINOTHIAZOLE. ECB. (2014), [cited June 23, 2022]; 3(6): 559-562.



Harvard Style

Mahmoud Najim Al-Jibouri, Fadhil R. Hafidh, Anaam Majeed Rasheed (2014) SYNTHESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH TRIDENTATE N3 DONOR SCHIFF BASE DERIVED FROM 2-AMINOTHIAZOLE. ECB, 3 (6), 559-562.



Turabian Style

Mahmoud Najim Al-Jibouri, Fadhil R. Hafidh, Anaam Majeed Rasheed. 2014. SYNTHESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH TRIDENTATE N3 DONOR SCHIFF BASE DERIVED FROM 2-AMINOTHIAZOLE. European Chemical Bulletin, 3 (6), 559-562.



Chicago Style

Mahmoud Najim Al-Jibouri, Fadhil R. Hafidh, Anaam Majeed Rasheed. "SYNTHESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH TRIDENTATE N3 DONOR SCHIFF BASE DERIVED FROM 2-AMINOTHIAZOLE." European Chemical Bulletin 3 (2014), 559-562.



MLA (The Modern Language Association) Style

Mahmoud Najim Al-Jibouri, Fadhil R. Hafidh, Anaam Majeed Rasheed. "SYNTHESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH TRIDENTATE N3 DONOR SCHIFF BASE DERIVED FROM 2-AMINOTHIAZOLE." European Chemical Bulletin 3.6 (2014), 559-562. Print.



APA (American Psychological Association) Style

Mahmoud Najim Al-Jibouri, Fadhil R. Hafidh, Anaam Majeed Rasheed (2014) SYNTHESIS AND CHARACTERIZATION OF SOME TRANSITION METAL COMPLEXES WITH TRIDENTATE N3 DONOR SCHIFF BASE DERIVED FROM 2-AMINOTHIAZOLE. European Chemical Bulletin, 3 (6), 559-562.