The construction industry is experiencing a transformative shift propelled by Additive Manufacturing (AM), commonly known as 3D printing. Despite widespread adoption in various sectors, the construction industry has been cautiously exploring AM's potential. This paper investigates the transformative power of AM, particularly in 3D Concrete Printing (3D-CP) using geopolymer binders. Historically, construction relied on conventional methods like pouring concrete into formworks. However, AM offers compelling advantages, including unparalleled design freedom, heightened safety, cost efficiency, waste reduction, and accelerated project timelines. Within the domain of 3D-CP, our focus is on powder-based techniques, involving precise deposition of powdered materials to craft intricate architectural forms. The synergy of these technologies with concrete opens doors to innovative construction possibilities. Our research delves into powder-based 3D Concrete Printing (PB-3D-CP), with a specific emphasis on geopolymer-based powders. Through a thorough exploration of experimental methodologies, we investigate particle size distributions, bed surface quality, densities, wettability, and mechanical properties. Our objective is to unearth insights that not only advance our understanding of this technology but also contribute to the broader discussion on the convergence of AM and construction.